Title
Effects of combined chemical and hydrothermal pretreatment on papyrus cellulose structure
Authors
PITIPORN MANOKHOON, KHATHAPON PINPATTHANAPONG, NITHINART C. JUNTADECH and THANEEYA RANGSEESURIYACHAI

Received August 3, 2023
Published Volume 57 Issue 9-10 September-December
Keywords papyrus, cellulose fiber, alkaline pretreatment, hydrothermal pretreatment

Abstract
Papyrus (Cyperus papyrus L.) is a lignocellulosic plant suitable for many applications when properly pretreated. This study explores the potential of a two-stage pretreatment (combining hydrothermal and chemical methods) on the characteristics of cellulose fibers derived from papyrus. One-stage and two-stage pretreatments were compared, utilizing sodium hydroxide (NaOH) and ferric chloride (FeCl3) chemical solutions at a 3% (w/v) concentration. Chemical pretreatment was employed for one-stage processing, while hydrothermal pretreatment was introduced prior to chemical pretreatment. As the liquid hot-water process intensified, significant changes in chemical composition and morphology occurred. Hydrothermal pretreatment partially eliminates hemicelluloses and lignin, while increasing the cellulose content and enhancing fiber crystallinity. Following the pulping and bleaching stages, it was determined that the FeCl3-based two-stage pretreatment exhibited the greatest potential for cellulose recovery and hemicelluloses and lignin removal, yielding the highest crystallinity index.